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The multiplication factor, k, is defined as (see nuclear chain reaction): k = number of neutrons in one generation / number of neutrons in preceding generation If k is greater than 1, the chain reaction is supercritical, and the neutron population will grow exponentially. If k is less than 1, the chain reaction is subcritical, and the ...
Rate constants from reacting the lightest and the heaviest hydrogen analogs with 1 H 2 were then used to calculate k 0.11 /k 4.1, in which there is a 36.4× difference in isotopic mass. For this reaction, isotopic substitution happens to produce an IKIE, and the authors report a KIE as low as 1.74×10 −4, the smallest KIE ever reported. [59]
If k = 1, the chain reaction is critical and the neutron population will remain constant. In an infinite medium, neutrons cannot leak out of the system and the multiplication factor becomes the infinite multiplication factor, k = k ∞ {\displaystyle k=k_{\infty }} , which is approximated by the four-factor formula.
where: k 1 is the rate coefficient for the reaction that consumes A and B; k −1 is the rate coefficient for the backwards reaction, which consumes P and Q and produces A and B. The constants k 1 and k −1 are related to the equilibrium coefficient for the reaction (K) by the following relationship (set v=0 in balance):
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
Equilibrium isotope fractionation is the partial separation of isotopes between two or more substances in chemical equilibrium. Equilibrium fractionation is strongest at low temperatures, and (along with kinetic isotope effects) forms the basis of the most widely used isotopic paleothermometers (or climate proxies): D/H and 18 O/ 16 O records from ice cores, and 18 O/ 16 O records from calcium ...
Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...