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PV work is often measured in units of litre-atmospheres where 1 L·atm = 101.325 J. However, the litre-atmosphere is not a recognized unit in the SI system of units, which measures P in pascals (Pa), V in m 3, and PV in joules (J), where 1 J = 1 Pa·m 3. PV work is an important topic in chemical thermodynamics.
In physics, Hooke's law is an empirical law which states that the force (F) needed to extend or compress a spring by some distance (x) scales linearly with respect to that distance—that is, F s = kx, where k is a constant factor characteristic of the spring (i.e., its stiffness), and x is small compared to the total possible deformation of the spring.
For a stretched spring fixed at one end obeying Hooke's law, the elastic potential energy is Δ E p = 1 2 k ( r 2 − r 1 ) 2 {\displaystyle \Delta E_{p}={\frac {1}{2}}k(r_{2}-r_{1})^{2}} where r 2 and r 1 are collinear coordinates of the free end of the spring, in the direction of the extension/compression, and k is the spring constant.
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
In some fields such as physical chemistry, positive work is conventionally considered work done on the system rather than by the system, and the law is expressed as = +. Second law of thermodynamics The entropy of an isolated system never decreases: d S ≥ 0 {\displaystyle dS\geq 0} for an isolated system.
Chemical potential energy is a form of potential energy related to the structural arrangement of atoms or molecules. This arrangement may be the result of chemical bonds within a molecule or otherwise. Chemical energy of a chemical substance can be transformed to other forms of energy by a chemical reaction. As an example, when a fuel is burned ...
WASHINGTON (Reuters) -U.S. President-elect Donald Trump greeted and shook hands on Thursday with his estranged former vice president Mike Pence, as current and former administrations gathered at ...
Work other than p dV may be added, e.g., for electrochemical cells, or f dx work in elastic materials and in muscle contraction. Other forms of work which must sometimes be considered are stress-strain, magnetic, as in adiabatic demagnetization used in the approach to absolute zero, and work due to electric polarization.