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In the chemical process industry, pyrolysis refers to a partial thermal degradation of carbonaceous materials that takes place in an inert (oxygen free) atmosphere and produces both gases, liquids and solids. The pyrolysis can be extended to full gasification that produces mainly gaseous output, [11] often with the addition of e.g. water steam ...
Pyrolysis oil, sometimes also known as biocrude or bio-oil, is a synthetic fuel with few industrial application and under investigation as substitute for petroleum.It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about 500 °C (900 °F) with subsequent cooling, separation from the aqueous phase and other processes.
Catalytic fast pyrolysis is a fast process in which the cellulose is broken down to a liquid biofuel. In this approach the cellulose is heated to 500 degrees Celsius in less than one second in a chamber to break apart the molecules. The catalyst forms chemical reactions that remove oxygen bonds and form carbon rings
As early as the 1920s, the concept of using hot water and alkali catalysts to produce oil out of biomass was proposed. [6] In 1939, U.S. patent 2,177,557, [7] described a two-stage process in which a mixture of water, wood chips, and calcium hydroxide is heated in the first stage at temperatures in a range of 220 to 360 °C (428 to 680 °F), with the pressure "higher than that of saturated ...
Pyrolysis gasoline or pygas is a naphtha-range product with high aromatics content. [1] It is a by-product of high temperature naphtha cracking during ethylene and propylene production, a high octane number mixture that contains aromatics from the aromatization reactions, olefins , and paraffins ranging from C5s to C12s.
Dry distillation is the heating of solid materials to produce gaseous products (which may condense into liquids or solids). The method may involve pyrolysis or thermolysis, or it may not (for instance, a simple mixture of ice and glass could be separated without breaking any chemical bonds, but organic matter contains a greater diversity of molecules, some of which are likely to break).
A specific method of pyrolysis of biomass, termed "fast pyrolysis," converts particles of biomass to about 10% carbon-rich solid called char, about 15% gases such as carbon dioxide, and about 70% a mixture of organic compounds commonly referred to as "bio-oil" at 500 °C in 1–2 seconds. [1]
Three main carbonaceous products are generated during pyrolysis, which can be stored subsequently in different ways to produce negative emissions: a solid biochar for various applications, a pyrolytic liquid (bio-oil) pumped into depleted fossil oil repositories, and permanent-pyrogas (dominated by the combustible gases CO, H 2 and CH 4) that ...
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