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Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the ...
For example, oxygen makes up about 8 / 9 of the mass of any sample of pure water, while hydrogen makes up the remaining 1 / 9 of the mass: the mass of two elements in a compound are always in the same ratio. Along with the law of multiple proportions, the law of definite proportions forms the basis of stoichiometry. [1]
Within chemistry, a Job plot, otherwise known as the method of continuous variation or Job's method, is a method used in analytical chemistry to determine the stoichiometry of a binding event. The method is named after Paul Job and is also used in instrumental analysis and advanced chemical equilibrium texts and research articles.
The generalisation of the law of mass action, in terms of affinity, to equilibria of arbitrary stoichiometry was a bold and correct conjecture. The hypothesis that reaction rate is proportional to reactant concentrations is, strictly speaking, only true for elementary reactions (reactions with a single mechanistic step), but the empirical rate ...
The Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of ... P ratio can vary anywhere from 6:1 to 60:1. While understanding this problem ...
Air–fuel equivalence ratio, λ (lambda), is the ratio of actual AFR to stoichiometry for a given mixture. λ = 1.0 is at stoichiometry, rich mixtures λ < 1.0, and lean mixtures λ > 1.0. There is a direct relationship between λ and AFR. To calculate AFR from a given λ, multiply the measured λ by the stoichiometric AFR for that fuel.
In physical chemistry and chemical engineering, extent of reaction is a quantity that measures the extent to which the reaction has proceeded. Often, it refers specifically to the value of the extent of reaction when equilibrium has been reached.
In chemistry, a mole map is a graphical representation of an algorithm that compares molar mass, number of particles per mole, and factors from balanced equations or other formulae. [1] They are often used in undergraduate-level chemistry courses as a tool to teach the basics of stoichiometry and unit conversion. [2] [3] [4]
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