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Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and selenium, as well.
Main group organometallic chemistry concerns the preparation and properties of main-group elements directly bonded to carbon. The inventory is large. The inventory is large. The compounds exhibit a wide range of properties, including ones that are water-stable and others that are pyrophoric . [ 1 ]
Group 2 organometallic chemistry refers to the organic derivativess of any group 2 element. It is a subtheme to main group organometallic chemistry . [ 2 ] [ 3 ] By far the most common group 2 organometallic compounds are the magnesium-containing Grignard reagents which are widely used in organic chemistry .
In organometallic chemistry, the isolobal principle (more formally known as the isolobal analogy) is a strategy used to relate the structure of organic and inorganic molecular fragments in order to predict bonding properties of organometallic compounds. [1]
Organocopper chemistry is the study of the physical properties, reactions, and synthesis of organocopper compounds, which are organometallic compounds containing a carbon to copper chemical bond. [ 1 ] [ 2 ] [ 3 ] They are reagents in organic chemistry .
This area of organometallic chemistry was first developed in the 1950s. Bent metallocenes are represented by compounds of the type [MCp 2 L x]. Some are catalysts for ethylene polymerization. [3] Metallocenes are often thermally stable, and find use as catalysts in various types of reactions.
Organoplatinum chemistry is the chemistry of organometallic compounds containing a carbon to platinum chemical bond, and the study of platinum as a catalyst in organic reactions. [ 1 ] [ 2 ] [ 3 ] Organoplatinum compounds exist in oxidation state 0 to IV, with oxidation state II most abundant.
Zeise's salt was one of the first organometallic compounds to be reported. [6] It was discovered by William Christopher Zeise, a professor at the University of Copenhagen, who prepared this compound in 1830 while investigating the reaction of PtCl 4 with boiling ethanol.