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Ammonium chloride is an inorganic chemical compound with the chemical formula N H 4 Cl, also written as [NH 4]Cl. It is an ammonium salt of hydrogen chloride. It consists of ammonium cations [NH 4] + and chloride anions Cl −. It is a white crystalline salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic.
The reaction can be demonstrated by starting with solutions of potassium cyanate and ammonium chloride which are mixed, heated and cooled again. An additional proof of the chemical transformation is obtained by adding a solution of oxalic acid which forms urea oxalate as a white precipitate. [3]
For example, in ammonium chloride solution, NH + 4 is the main influence for acidic solution. It has greater K a value compared to that of water molecules; K a of NH + 4 is 5.6 × 10 −10, and K w of H 2 O is 1.0 × 10 −14. This ensures its deprotonation when reacting with water, and is responsible for the pH below 7 at room temperature.
Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −
This reaction involves the preparation of aldehydes (R-CHO) from nitriles (R-CN) using tin(II) chloride (SnCl 2), hydrochloric acid (HCl) and quenching the resulting iminium salt ([R-CH=NH 2] + Cl −) with water (H 2 O). [1] [2] During the synthesis, ammonium chloride is also produced. Stephen aldehyde synthesis
Most simple ammonium salts are very soluble in water. An exception is ammonium hexachloroplatinate, the formation of which was once used as a test for ammonium. The ammonium salts of nitrate and especially perchlorate are highly explosive, in these cases, ammonium is the reducing agent. In an unusual process, ammonium ions form an amalgam.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In aqueous solution, chloramine slowly decomposes to dinitrogen and ammonium chloride in a neutral or mildly alkaline (pH ≤ 11) medium: 3 NH 2 Cl → N 2 + NH 4 Cl + 2 HCl. However, only a few percent of a 0.1 M chloramine solution in water decomposes according to the