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Diphenyl disulfide is the chemical compound with the formula (C 6 H 5 S) 2. This colorless crystalline material is often abbreviated Ph 2 S 2. It is one of the more commonly encountered organic disulfides in organic synthesis. Minor contamination by thiophenol is responsible for the disagreeable odour associated with this compound.
Diphenyl sulfide and its analogues can also be produced by coupling reactions using metal catalysts. [5] It can also be prepared by reduction of diphenyl sulfone. [6] Diphenyl sulfide is a product of the photodegradation of the fungicide edifenphos. [7] Diphenyl sulfide is a precursor to triaryl sulfonium salts, which are used as photoinitiators.
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Thiophenol is an organosulfur compound with the formula C 6 H 5 SH, sometimes abbreviated as PhSH. This foul-smelling colorless liquid is the simplest aromatic thiol.The chemical structures of thiophenol and its derivatives are analogous to phenols, where the oxygen atom in the hydroxyl group (-OH) bonded to the aromatic ring in phenol is replaced by a sulfur atom.
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General structure of a disulfide Organic disulfides are chemical compounds with the general structure RSSR'. Wikimedia Commons has media related to Organic disulfides .
The oxidation and reduction of protein disulfide bonds in vitro also generally occurs via thiol–disulfide exchange reactions. Typically, the thiolate of a redox reagent such as glutathione, dithiothreitol attacks the disulfide bond on a protein forming a mixed disulfide bond between the protein and the reagent. This mixed disulfide bond when ...
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