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The MOFs, deemed MOF-1114, MOF-1115, MOF-1130, and MOF-1131, are composed of octahedral SBUs bridged by amino functionalized dicarboxylate linkers. The amino groups on the linkers served as sites for covalent PSM reactions with either salicylaldehyde or 3-hydroxynaphthalene-2-carboxaldehyde.
Ultrathin sheets of Co-HAB MOF have been found to be catalytically active for oxygen evolution reaction (OER). Overpotential for this MOF was 310 mV at 10 mA cm −2 in 1M KOH. Authors claimed that the ultrathin sheets were better than nanoparticles/thick sheets/bulk Co-HAB MOF because of favourable electrode kinetics. [22]
The divalent metal carboxylate based frameworks MOF-5 and HKUST-1 are examples of prototypical MOF materials and triggered a huge growth in the field of metal-organic frameworks. A keyword search for “metal-organic frameworks” registers>1,600 publications in 2010 and >2,000 for 2011, a strong indication of the worldwide interest in this ...
The crystal form of ZIF, or MOF in general, is known for its porosity, but is difficult to mass-produce and incorporate in actual applications due to unavoidable intercrystalline defects. [35] There are several interesting characters about ZIF glasses addressing those challenges to potentially realize promised applications achievable.
Some metal-organic frameworks (MOF) display large structural changes as a response to external stimuli, and such modifications of their structure can, in turn, lead to drastic changes in their physical and chemical properties.
Due to the tool-box like design of metal-organic framework materials, other organic molecules, which are structurally similar to biphenyl-4,4'-dicarboxylate, have also been used as linker molecules for the synthesis of functionalized DUT-5 materials, which contain uncoordinated functional groups in their framework structure.
MOF-5 or IRMOF-1 is a cubic metal–organic framework compound with the formula Zn 4 O(BDC) 3, where BDC 2− = 1,4-benzodicarboxylate (MOF-5). [1] It was first synthesized by graduate students and post doctoral scholars in the lab of Omar M. Yaghi .
MOF may refer to: Managed Object Format, a textual representation of the Distributed Management Task Force (DMTF) Common Information Model (CIM) Meta-Object Facility, a meta-model used to formally define Unified Modeling Language (UML) Metal–organic framework, a chemical compound formed of metal ions and organic chemical components
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