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The kinetic derivation applies to gas-phase adsorption. However, it has been mistakenly applied to solutions. The multiple-adsorbate case is covered in the competitive adsorption sub-section. The model assumes adsorption and desorption as being elementary processes, where the rate of adsorption r ad and the rate of desorption r d are given by
4.2 Kinetic model. 5 Plasma science and ... It is the most abundant form of ordinary matter in the universe, ... Langmuir also introduced the term "plasma" as a ...
Irving Langmuir (/ ˈ l æ ŋ m j ʊər /; [2] January 31, 1881 – August 16, 1957) was an American chemist, physicist, and metallurgical engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry .
The Hertz–Knudsen equation describes the non-dissociative adsorption of a gas molecule on a surface by expressing the variation of the number of molecules impacting on the surfaces per unit of time as a function of the pressure of the gas and other parameters which characterise both the gas phase molecule and the surface: [1] [2]
The langmuir (symbol: L) is a unit of exposure (or dosage) to a surface (e.g. of a crystal) and is used in ultra-high vacuum (UHV) surface physics to study the adsorption of gases. It is a practical unit, and is not dimensionally homogeneous, and so is used only in this field. It is named after American physicist Irving Langmuir.
The following reactions follow a Langmuir–Hinshelwood mechanism: [4] 2 CO + O 2 → 2 CO 2 on a platinum catalyst. CO + 2H 2 → CH 3 OH on a ZnO catalyst. C 2 H 4 + H 2 → C 2 H 6 on a copper catalyst. N 2 O + H 2 → N 2 + H 2 O on a platinum catalyst. C 2 H 4 + 1 / 2 O 2 → CH 3 CHO on a palladium catalyst. CO + OH → CO 2 + H ...
Plasma oscillations, also known as Langmuir waves (after Irving Langmuir), are rapid oscillations of the electron density in conducting media such as plasmas or metals in the ultraviolet region. The oscillations can be described as an instability in the dielectric function of a free electron gas. The frequency depends only weakly on the ...
Some physicists, such as Lawrence Krauss, Stephen Hawking or Alexander Vilenkin, call or called this state "a universe from nothingness", although the zero-energy universe model requires both a matter field with positive energy and a gravitational field with negative energy to exist. [2] The hypothesis is broadly discussed in popular sources.