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Propylene oxide is an acutely toxic and carcinogenic organic compound with the molecular formula C 3 H 6 O. This colourless volatile liquid with an odour similar to ether , is produced on a large scale industrially.
The dominant epoxides industrially are ethylene oxide and propylene oxide, which are produced respectively on the scales of approximately 15 and 3 million tonnes/year. [2] Aside from ethylene oxide, most epoxides are generated when peroxidized reagents donate a single oxygen atom to an alkene. Safety considerations weigh on these reactions ...
Ethylene oxide scrubber: After the gaseous stream from the main reactor, containing ethylene oxide (1–2%) and CO 2 (5%), is cooled, it is then passed to the ethylene oxide scrubber. Here, water is used as the scrubbing media which scrubs away majority of ethylene oxide along with some amounts of CO 2 , N 2 , CH 2 =CH 2 , CH 4 and aldehydes ...
In the IUPAC system, the name ethylene is reserved for the divalent group -CH 2 CH 2-. Hence, names like ethylene oxide and ethylene dibromide are permitted, but the use of the name ethylene for the two-carbon alkene is not. Nevertheless, use of the name ethylene for H 2 C=CH 2 (and propylene for H 2 C=CHCH 3) is still prevalent among chemists ...
Propylene oxide is more hydrophobic than ethylene oxide and its inclusion at low levels can significantly affect the properties of the surfactant. In particular ethoxylated fatty alcohols which have been 'capped' with ~1 propylene oxide unit are extensively marketed as defoamers.
Propylene is also used to produce isopropyl alcohol (propan-2-ol), acrylonitrile, propylene oxide, and epichlorohydrin. [18] The industrial production of acrylic acid involves the catalytic partial oxidation of propylene. [19] Propylene is an intermediate in the oxidation to acrylic acid.
Polypropylene glycol is produced by ring-opening polymerization of propylene oxide.The initiator is an alcohol and the catalyst a base, usually potassium hydroxide.When the initiator is ethylene glycol or water the polymer is linear.
The usual manifestation of this reaction is ethoxylation of alcohols (ROH), in which case ethylene oxide is the alkoxylating agent: ROH + C 2 H 4 O → ROCH 2 CH 2 OH. Another industrially significant epoxide is propylene oxide (PO, OCH 2 CHCH 3). PO is mainly used for alkoxylation to produce polyether polyols.