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Confederate monument at Union County Courthouse. Union County is a county located on the central southern border of the U.S. state of Arkansas.As of the 2020 census, the population was 39,054. [1]
Cane Hill College in Canehill was the first college in Arkansas, prior to the University of Arkansas's founding in 1871. A 2012 study found 84.2% of Washington County residents over age 25 held a high school degree or higher and 31.9% held a bachelor's degree or higher.