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These clusters consist of at least two different (semi)metallic elements, and possess more direct metal-metal than metal-ligand contacts. The suffix "oid" designate that such clusters possess at a molecular scale, atom arrangements that appear in bulk intermetallic compounds with high coordination numbers of the atoms, such as for example in ...
The coinage metals comprise those metallic chemical elements and alloys which have been used to mint coins. Historically, most coinage metals are from the three nonradioactive members of group 11 of the periodic table: copper, silver and gold. Copper is usually augmented with tin or other metals to form bronze.
Group 11 is also known as the coinage metals, due to their usage in minting coins [2] —while the rise in metal prices mean that silver and gold are no longer used for circulating currency, remaining in use for bullion, copper remains a common metal in coins to date, either in the form of copper clad coinage or as part of the cupronickel alloy.
Larger clusters, containing both iron and nickel, are most stable with Fe atoms located in the inner parts of the cluster and Ni metals on outside. In other terms, when iron and nickel form body-centered cubic structures the preferred position of Ni atoms is at the surface, instead of at the center of the cluster, as it is energetically ...
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One example of a superatom is the cluster Al 13 −. [2] Sodium atoms, when cooled from vapor, naturally condense into clusters, preferentially containing a magic number of atoms (2, 8, 20, 40, 58, etc.), with the outermost electron of each atom entering an orbital encompassing all the atoms in the cluster.
The metal atoms define the vertices of an octahedron. The overall point group symmetry is O h. Each face of the octahedron is capped with a chalcohalide and eight such atoms are at the corners of a cube. For this reason this geometry is called a face capped octahedral cluster. Examples of this type of clusters are the Re 6 S 8 Cl 6 4− anion.
In some cases the transition metal will cap the face of the cluster. Another mode of reaction is the formation of endohedral complexes where the metal is encapsulated inside the cluster. These types of complexes lend themselves to comparison with the solid state structure of the corresponding Zintl phase. [16]