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  2. Charge-transfer complex - Wikipedia

    en.wikipedia.org/wiki/Charge-transfer_complex

    In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...

  3. Charge transfer coefficient - Wikipedia

    en.wikipedia.org/wiki/Charge_transfer_coefficient

    They appear in the Butler–Volmer equation and related expressions. The symmetry factor and the charge transfer coefficient are dimensionless. [1] According to an IUPAC definition, [2] for a reaction with a single rate-determining step, the charge transfer coefficient for a cathodic reaction (the cathodic transfer coefficient, α c) is defined as:

  4. Knoevenagel condensation - Wikipedia

    en.wikipedia.org/wiki/Knoevenagel_condensation

    A Knoevenagel condensation is demonstrated in the reaction of 2-methoxybenzaldehyde 1 with the thiobarbituric acid 2 in ethanol using piperidine as a base. [7] The resulting enone 3 is a charge transfer complex molecule.

  5. Interpolymer complexes - Wikipedia

    en.wikipedia.org/wiki/Interpolymer_complexes

    Interpolymer complexes (IPC) are the products of non-covalent interactions between complementary unlike macromolecules in solutions. [1] There are four types of these complexes: Interpolyelectrolyte complexes (IPEC) or polyelectrolyte complexes (PEC) [2] Hydrogen-bonded interpolymer complexes [3] Stereocomplexes [4] Charge-transfer complexes [5]

  6. Cross-coupling reaction - Wikipedia

    en.wikipedia.org/wiki/Cross-coupling_reaction

    The oxidative addition of an organic halide (RX) to L n M gives L n MR(X). Subsequently, the second partner undergoes transmetallation with a source of R' −. The final step is reductive elimination of the two coupling fragments to regenerate the catalyst and give the

  7. Organic semiconductor - Wikipedia

    en.wikipedia.org/wiki/Organic_semiconductor

    In the 1950s, researchers discovered that polycyclic aromatic compounds formed semi-conducting charge-transfer complex salts with halogens. In particular, high conductivity of 0.12 S/cm was reported in perylene–iodine complex in 1954. [3] This finding indicated that organic compounds could carry current.

  8. Rearrangement reaction - Wikipedia

    en.wikipedia.org/wiki/Rearrangement_reaction

    In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...

  9. Conductive polymer - Wikipedia

    en.wikipedia.org/wiki/Conductive_polymer

    Broad research on salts of charge transfer complexes continues today. While these compounds were technically not polymers, this indicated that organic compounds can carry current. While organic conductors were previously intermittently discussed, the field was particularly energized by the prediction of superconductivity [ 10 ] following the ...

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