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In physics, Hooke's law is an empirical law which states that the force (F) needed to extend or compress a spring by some distance (x) scales linearly with respect to that distance—that is, F s = kx, where k is a constant factor characteristic of the spring (i.e., its stiffness), and x is small compared to the total possible deformation of the spring.
1.438 776 877... × 10 −2 m⋅K: 0 [12] [e] Wien wavelength displacement law constant: 2.897 771 955... × 10 −3 m⋅K: 0 [13] ′ [f] Wien frequency displacement law constant: 5.878 925 757... × 10 10 Hz⋅K −1: 0 [14] Wien entropy displacement law constant 3.002 916 077... × 10 −3 m⋅K: 0
the concentration of water may be taken as being constant and the formation of the hydronium ion is implicit. AH ⇌ A − + H + Water concentration is omitted from expressions defining equilibrium constants, except when solutions are very concentrated. = [] [] [] (K defined as a dissociation constant)
Some constants, such as the ideal gas constant, R, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as K f (the freezing point depression constant, or cryoscopic constant ), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore ...
In other words, reactant A and product B are forming into one another based on reaction rate constants k and k'. To solve for the concentration of A, recognize that the forward reaction causes the concentration of A to decrease over time, whereas the reverse reaction (′) causes the concentration of A to increase over time.
The different units are accounted for in using either the gas constant, R, or the Boltzmann constant, k B, as the multiplier of temperature T. The unit of the pre-exponential factor A are identical to those of the rate constant and will vary depending on the order of the reaction. If the reaction is first order it has the unit s −1, and for ...
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The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".