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DAST is prepared by the reaction of diethylaminotrimethylsilane and sulfur tetrafluoride: [3] Et 2 NSiMe 3 + SF 4 → Et 2 NSF 3 + Me 3 SiF. The original paper calls for trichlorofluoromethane (Freon-11) as a solvent. [4] Diethyl ether is a green alternative that can be used with no decrease in yield. [5]
Thiophenol is an organosulfur compound with the formula C 6 H 5 SH, sometimes abbreviated as PhSH. This foul-smelling colorless liquid is the simplest aromatic thiol.The chemical structures of thiophenol and its derivatives are analogous to phenols, where the oxygen atom in the hydroxyl group (-OH) bonded to the aromatic ring in phenol is replaced by a sulfur atom.
Sulfur hexafluoride or sulphur hexafluoride (British spelling) is an inorganic compound with the formula SF 6. It is a colorless, odorless, non-flammable, and non-toxic gas. SF 6 has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom. It is a hypervalent molecule. [citation needed] Typical for a nonpolar ...
An example SDS, including guidance for handling a hazardous substance and information on its composition and properties. A safety data sheet (SDS), [1] material safety data sheet (MSDS), or product safety data sheet (PSDS) is a document that lists information relating to occupational safety and health for the use of various substances and products.
Mustard gas or sulfur mustard are names commonly used for the organosulfur chemical compound bis(2-chloroethyl) sulfide, which has the chemical structure S(CH 2 CH 2 Cl) 2, as well as other species. In the wider sense, compounds with the substituents −SCH 2 CH 2 X or −N(CH 2 CH 2 X) 2 are known as sulfur mustards or nitrogen mustards ...
Dimethyl sulfide has a characteristic odor commonly described as cabbage-like.It becomes highly disagreeable at even quite low concentrations. Some reports claim that DMS has a low olfactory threshold that varies from 0.02 to 0.1 ppm [clarification needed] between different persons, but it has been suggested that the odor attributed to dimethyl sulfide may in fact be due to disulfides ...
Sulfur dichloride is the chemical compound with the formula SCl 2. This cherry-red liquid is the simplest sulfur chloride and one of the most common, and it is used as a precursor to organosulfur compounds. It is a highly corrosive and toxic substance, and it reacts on contact with water to form chlorine-containing acids.
Sulfur tetrafluoride is a chemical compound with the formula S F 4. It is a colorless corrosive gas that releases dangerous hydrogen fluoride gas upon exposure to water or moisture. Sulfur tetrafluoride is a useful reagent for the preparation of organofluorine compounds , [ 3 ] some of which are important in the pharmaceutical and specialty ...