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Calone, a derivative of 4-methylcatechol, is known in the fragrance industry as "watermelon ketone" for its distinctive odor. [ 3 ] The brand of low-temperature coke used as a smokeless fuel Coalite obtains homocatechol from ammoniacal liquor by solvent extraction, distillation and crystallisation .
C 6 H 4 (OH) 2 + XCl 2 → C 6 H 4 (O 2 X) + 2 HCl where X = PCl or POCl; SO 2; CO. Basic solutions of catechol react with iron(III) to give the red [Fe(C 6 H 4 O 2) 3] 3−. Ferric chloride gives a green coloration with the aqueous solution, while the alkaline solution rapidly changes to a green and finally to a black color on exposure to the ...
There are three structural isomers: 1,2-dihydroxybenzene (the ortho isomer) is commonly known as catechol, 1,3-dihydroxybenzene (the meta isomer) is commonly known as resorcinol, and 1,4-dihydroxybenzene (the para isomer) is commonly known as hydroquinone. [1]
Synthesis from the latter chemical is accomplished through a condensation reaction with glyoxylic acid followed by cleaving the resulting α-hydroxy acid with an oxidizing agent. [3] [4] [5] Synthesis from catechol requires an additional step, Williamson ether synthesis using dichloromethane. [6]
Pyrogallic acid 1,2,3-Benzenetriol [1] ... 1.453 g/cm 3 (4 °C) [1] Melting point: 125.5 °C (257.9 °F; ... Catechol; Gallacetophenone (2,3,4-trihydroxyacetophenone)
ch 3 c 6 h 4 so 3 h + 2 naoh → ch 3 c 6 h 4 oh + na 2 so 3 + h 2 o Other methods for the production of p -cresol include chlorination of toluene followed by hydrolysis. In the cymene-cresol process, toluene is alkylated with propene to give p -cymene , which can be oxidatively dealkylated in a manner similar to the cumene process .
Triazabicyclodecene (1,5,7-triazabicyclo[4.4.0]dec-5-ene or TBD) is an organic compound consisting of a bicyclic guanidine. For a charge-neutral compound, it is a relatively strong base that is effective for a variety of organic transformations. TBD is colorless solid that is soluble in a variety of solvents. [4]
[3] mTBD, like 1,5,7-triazabicyclo[4.4.0]dec-5-ene and other guanidine super bases, can be used as a catalyst in a variety of chemical reactions. [4] It also reacts with CO 2, [5] which could make it useful for carbon capture and storage. [6] When brought into contact with some acids, mTBD reacts to form an ionic liquid.