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The reaction will only be allowed if the total entropy change of the universe is zero or positive. This is reflected in a negative ΔG, and the reaction is called an exergonic process. If two chemical reactions are coupled, then an otherwise endergonic reaction (one with positive ΔG) can be made to happen.
The change of Gibbs free energy (ΔG) in an exergonic reaction (that takes place at constant pressure and temperature) is negative because energy is lost (2). In chemical thermodynamics, an exergonic reaction is a chemical reaction where the change in the free energy is negative (there is a net release of free energy). [1]
If these two signs are the same (both positive or both negative), then the sign of ΔG will change from positive to negative (or vice versa) at the temperature T = ΔH/ΔS. In cases where Δ G is: negative, the process is spontaneous and may proceed in the forward direction as written.
There is a negative sign because a spontaneous reaction has a negative Gibbs free energy ΔG and a positive potential E. The Gibbs free energy is related to the entropy by G = H − TS, where H is the enthalpy and T is the temperature of the system.
Thus, a negative value of the change in free energy is a necessary condition for a process to be spontaneous; this is the most useful form of the second law of thermodynamics in chemistry. In chemical equilibrium at constant T and p without electrical work, d G = 0.
All physical and chemical systems in the universe follow the second law of thermodynamics and proceed in a downhill, i.e., exergonic, direction.Thus, left to itself, any physical or chemical system will proceed, according to the second law of thermodynamics, in a direction that tends to lower the free energy of the system, and thus to expend energy in the form of work.
An exergonic process is one which there is a positive flow of energy from the system to the surroundings. This is in contrast with an endergonic process. [1] Constant pressure, constant temperature reactions are exergonic if and only if the Gibbs free energy change is negative (∆G < 0).
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...