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Ethylene oxide scrubber: After the gaseous stream from the main reactor, containing ethylene oxide (1–2%) and CO 2 (5%), is cooled, it is then passed to the ethylene oxide scrubber. Here, water is used as the scrubbing media which scrubs away majority of ethylene oxide along with some amounts of CO 2 , N 2 , CH 2 =CH 2 , CH 4 and aldehydes ...
So-called noble metals, such as gold and platinum, resist direct chemical combination with oxygen, and substances like gold(III) oxide (Au 2 O 3) must be formed by an indirect route. The alkali metals and alkali earth metals all react spontaneously with oxygen when exposed to dry air to form oxides, and form hydroxides in the presence of oxygen ...
The silver salt 1 reacts with bromine to form the acyl hypohalite intermediate 2. Formation of the diradical pair 3 allows for radical decarboxylation to form the diradical pair 4, which recombines to form the organic halide 5. The trend in the yield of the resulting halide is primary > secondary > tertiary. [2] [3]
Simple epoxides are often referred to as oxides. Thus, the epoxide of ethylene (C 2 H 4) is ethylene oxide (C 2 H 4 O). Many compounds have trivial names; for instance, ethylene oxide is called "oxirane". Some names emphasize the presence of the epoxide functional group, as in the compound 1,2-epoxyheptane, which can also be called 1,2-heptene ...
Since phenols are acidic, they readily react with a strong base like sodium hydroxide to form phenoxide ions. The phenoxide ion will then substitute the –X group in the alkyl halide, forming an ether with an aryl group attached to it in a reaction with an S N 2 mechanism.
Ethenone reacts with methanal in the presence of catalysts such as Lewis acids (AlCl 3, ZnCl 2 or BF 3) to give β-propiolactone. [21] The technically most significant use of ethenone is the synthesis of sorbic acid by reaction with 2-butenal (crotonaldehyde) in toluene at about 50 °C in the presence of zinc salts of long-chain carboxylic acids.
Bromine water, Br 2. Bromine water is an oxidizing, intense brown mixture containing diatomic bromine (Br 2) dissolved in water (H 2 O). [1] It is often used as a reactive in chemical assays of recognition for substances which react with bromine in an aqueous environment with the halogenation mechanism, mainly unsaturated carbon compounds (carbon compounds with 1 or more double or triple bond(s)).
Several reagents can be substituted for bromine. Sodium hypochlorite, [4] lead tetraacetate, [5] N-bromosuccinimide, and (bis(trifluoroacetoxy)iodo)benzene [6] can effect a Hofmann rearrangement. The intermediate isocyanate can be trapped with various nucleophiles to form stable carbamates or other