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Nitric acid reacts with most metals, but the details depend on the concentration of the acid and the nature of the metal. Dilute nitric acid behaves as a typical acid in its reaction with most metals. Magnesium, manganese, and zinc liberate H 2: Mg + 2 HNO 3 → Mg(NO 3) 2 + H 2 Mn + 2 HNO 3 → Mn(NO 3) 2 + H 2 Zn + 2 HNO 3 → Zn(NO 3) 2 + H 2
Another method involves the reaction of urea, nitric acid and sulfuric acid: [54] 2 (NH 2) 2 CO + 2 HNO 3 + H 2 SO 4 → 2 N 2 O + 2 CO 2 + (NH 4) 2 SO 4 + 2 H 2 O. Direct oxidation of ammonia with a manganese dioxide-bismuth oxide catalyst has been reported: [55] cf. Ostwald process. 2 NH 3 + 2 O 2 → N 2 O + 3 H 2 O
Nitric acid is generated via the Ostwald process by oxidation of ammonia with air over a platinum catalyst at 700–850 °C (1,292–1,562 °F), ≈9 atm. Nitric oxide and nitrogen dioxide are intermediate in this conversion: [44] NH 3 + 2 O 2 → HNO 3 + H 2 O. Nitric acid is used for the production of fertilisers, explosives, and many ...
Safety data sheet (SDS) ... neutralizing free radicals by nitric oxide ... [65] [66] The sodium nitrite induces methemoglobinemia in swine, ...
Conversely, with some other catalysts, ethylene oxide may be reduced by hydrogen to ethylene with the yield up to 70%. The reduction catalysts include mixtures of zinc dust and acetic acid , of lithium aluminium hydride with titanium trichloride (the reducing agent is actually titanium dichloride , formed by the reaction between LiAlH 4 and ...
Methyl nitrate is a sensitive explosive.When ignited it burns extremely fiercely with a gray-blue flame. Methyl nitrate is a very strong explosive with a detonation velocity of 6,300 m/s, [8] like nitroglycerin, ethylene glycol dinitrate, and other nitrate esters.
Solutions of dinitrogen pentoxide in nitric acid can be seen as nitric acid with more than 100% concentration. The phase diagram of the system H 2 O − N 2 O 5 shows the well-known negative azeotrope at 60% N 2 O 5 (that is, 70% HNO 3), a positive azeotrope at 85.7% N 2 O 5 (100% HNO 3), and another negative one at 87.5% N 2 O 5 ("102% HNO 3 ...
The industrial production of ammonium nitrate entails the acid-base reaction of ammonia with nitric acid: [12] HNO 3 + NH 3 → NH 4 NO 3. The ammonia required for this process is obtained by the Haber process from nitrogen and hydrogen. Ammonia produced by the Haber process can be oxidized to nitric acid by the Ostwald process.