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The chirality of a molecule that has a helical, propeller, or screw-shaped geometry is called helicity [5] or helical chirality. [6] [7] The screw axis or the D n, or C n principle symmetry axis is considered to be the axis of chirality. Some sources consider helical chirality to be a type of axial chirality, [7] and some do not.
It is also rotationally invariant, in that a rotation applied to the system leaves the helicity unchanged. Helicity, however, is not Lorentz invariant; under the action of a Lorentz boost, the helicity may change sign. Consider, for example, a baseball, pitched as a gyroball, so that its spin axis is aligned with the direction of the pitch. It ...
The rule of mutual exclusion in molecular spectroscopy relates the observation of molecular vibrations to molecular symmetry.It states that no normal modes can be both Infrared and Raman active in a molecule that possesses a center of symmetry.
To see an in depth discussion of the two with examples, which also shows how chirality and helicity approach the same thing as speed approaches that of light, click the link entitled "Chirality and Helicity in Depth" on the same page. History of science: parity violation; Helicity, Chirality, Mass, and the Higgs (Quantum Diaries blog)
The two-component helicity eigenstates satisfy ^ (^) = (^) where are the Pauli matrices, ^ is the direction of the fermion momentum, = depending on whether spin is pointing in the same direction as ^ or opposite.
Magnetic helicity is a gauge-dependent quantity, because can be redefined by adding a gradient to it (gauge choosing).However, for perfectly conducting boundaries or periodic systems without a net magnetic flux, the magnetic helicity contained in the whole domain is gauge invariant, [15] that is, independent of the gauge choice.
Macroscopic examples of chirality are found in the plant kingdom, the animal kingdom and all other groups of organisms. A simple example is the coiling direction of any climber plant, which can grow to form either a left- or right-handed helix. In anatomy, chirality is found in the imperfect mirror image symmetry of many kinds of animal bodies.
The systematic naming for this class of compounds is based on the number of rings: [n]helicene is the structure consisting of n rings. According to IUPAC, only structures where n is at least 5 are considered helicenes. [1] Some specific compounds also have alternate or trivial names.