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A (Z)-group is a group faithfully represented as a doubly transitive permutation group in which no non-identity element fixes more than two points. A (ZT)-group is a (Z)-group that is of odd degree and not a Frobenius group , that is a Zassenhaus group of odd degree, also known as one of the groups PSL(2,2 k +1 ) or Sz(2 2 k +1 ) , for k any ...
A specific example of a M-Z bond wherein other L-ligands are present in the complex [7] Both uncharged transition metal complexes and anionic complexes lead to the required adducts with acidic boranes. On the right is a typical reaction of a Z-ligand where the electron deficit BPh 3 adds to the anionic Fe complex.
In organic chemistry, a group transfer reaction is a class of the pericyclic reaction where one or more groups of atoms is transferred from one molecule to another. Group transfer reactions can sometimes be difficult to identify when separate reactant molecules combine into a single product molecule (like in the ene reaction).
Periodic Videos (also known as The Periodic Table of Videos) is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table , with additional videos on other topics in chemistry and related fields.
In abstract algebra, the center of a group G is the set of elements that commute with every element of G. It is denoted Z(G), from German Zentrum, meaning center. In set-builder notation, Z(G) = {z ∈ G | ∀g ∈ G, zg = gz}. The center is a normal subgroup, Z(G) ⊲ G, and also a characteristic subgroup, but is not necessarily fully ...
These reactions are useful beyond simply expanding a ring because the exocyclic group attacked may also have other functionality appended to it besides the leaving group. The group to which the endocyclic bond migrates can also be selectively added to the ring based on the functionality already present, for example 1,2 addition into a cyclic ...
This argument applies equally to p-groups, where every element's order is a power of (but not necessarily every order is the same). One may use the abelian case of Cauchy's Theorem in an inductive proof [ 5 ] of the first of Sylow's theorems, similar to the first proof above, although there are also proofs that avoid doing this special case ...
Sir Martyn Poliakoff (born 16 December 1947) [3] is a British chemist known for his work on green chemistry and for being the main presenter on the popular YouTube channel Periodic Videos. [6] The core subjects of his academic work are supercritical fluids, [7] [8] infrared spectroscopy and lasers.