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  2. Basis set superposition error - Wikipedia

    en.wikipedia.org/wiki/Basis_set_superposition_error

    As the atoms of interacting molecules (or of different parts of the same molecule - intramolecular BSSE) [1] [2] approach one another, their basis functions overlap. Each monomer "borrows" functions from other nearby components, effectively increasing its basis set and improving the calculation of derived properties such as energy . [ 3 ]

  3. Rule of mutual exclusion - Wikipedia

    en.wikipedia.org/wiki/Rule_of_mutual_exclusion

    The rule arises because in a centrosymmetric point group, IR active modes, which must transform according to the same irreducible representation generated by one of the components of the dipole moment vector (x, y or z), must be of ungerade (u) symmetry, i.e. their character under inversion is -1, while Raman active modes, which transform ...

  4. Endomicroscopy - Wikipedia

    en.wikipedia.org/wiki/Endomicroscopy

    Endomicroscopy is a technique for obtaining histology-like images from inside the human body in real-time, [1] [2] [3] a process known as ‘optical biopsy’. [ 4 ] [ 5 ] It generally refers to fluorescence confocal microscopy , although multi-photon microscopy and optical coherence tomography have also been adapted for endoscopic use.

  5. Confocal endoscopy - Wikipedia

    en.wikipedia.org/wiki/Confocal_endoscopy

    Confocal endoscopy, or confocal laser endomicroscopy (CLE), is a modern imaging technique that allows the examination of real-time microscopic and histological features inside the body. In the word "endomicroscopy", endo- means "within" and -skopein means "to view or observe".

  6. Enantiomeric excess - Wikipedia

    en.wikipedia.org/wiki/Enantiomeric_excess

    This has led to informal use the two terms as interchangeable, especially because optical purity was the traditional way of measuring enantiomeric excess. However, other methods such as chiral column chromatography and NMR spectroscopy can now be used for measuring the amount of each enantiomer individually.

  7. Diiodotyrosine - Wikipedia

    en.wikipedia.org/wiki/Diiodotyrosine

    Chemical formula. C 9 H 9 I 2 NO 3 ... Two molecules of DIT combine to make the thyroid hormone thyroxine ... Toggle the table of contents.

  8. Pump–probe microscopy - Wikipedia

    en.wikipedia.org/wiki/Pump–probe_microscopy

    This is the same phenomenon used in two-photon microscopy (TPM), but there are two key features that distinguish pump–probe microscopy from TPM. First, since the molecule is not necessarily fluorescent, a photodetector measures the probe intensity. Therefore, the signal decreases as two-photon absorption occurs, the reverse of TPM. [3]

  9. Homochirality - Wikipedia

    en.wikipedia.org/wiki/Homochirality

    Homochirality is a uniformity of chirality, or handedness.Objects are chiral when they cannot be superposed on their mirror images. For example, the left and right hands of a human are approximately mirror images of each other but are not their own mirror images, so they are chiral.