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Radius of gyration (in polymer science)(, unit: nm or SI unit: m): For a macromolecule composed of mass elements, of masses , =1,2,…,, located at fixed distances from the centre of mass, the radius of gyration is the square-root of the mass average of over all mass elements, i.e.,
The radius of this circle, , can be determined by equating the magnitude of the Lorentz force to the centripetal force as = | |. Rearranging, the gyroradius can be expressed as = | |. Thus, the gyroradius is directly proportional to the particle mass and perpendicular velocity, while it is inversely proportional to the particle electric charge ...
Measurement of the scattering intensity at many angles allows calculation of the root mean square radius, also called the radius of gyration R g. By measuring the scattering intensity for many samples of various concentrations, the second virial coefficient, A 2 , can be calculated.
R is some length scale describing the chain conformation such as the radius of gyration or root-mean-square end-to-end distance of the chain. [2] Typically the pervaded volume is very large relative to the space actually occupied by the chain as most of the pervaded volume is usually filled with solvent or other chains. [1]
Area#Area formulas – Size of a two-dimensional surface; Perimeter#Formulas – Path that surrounds an area; List of second moments of area; List of surface-area-to-volume ratios – Surface area per unit volume; List of surface area formulas – Measure of a two-dimensional surface; List of trigonometric identities
where is the radius of gyration of the polymer, is the number of bond segments (equal to the degree of polymerization) of the chain and is the Flory exponent. For good solvent, ν ≈ 3 / 5 {\displaystyle \nu \approx 3/5} ; for poor solvent, ν = 1 / 3 {\displaystyle \nu =1/3} .
The generation of a bicylinder Calculating the volume of a bicylinder. A bicylinder generated by two cylinders with radius r has the volume =, and the surface area [1] [6] =.. The upper half of a bicylinder is the square case of a domical vault, a dome-shaped solid based on any convex polygon whose cross-sections are similar copies of the polygon, and analogous formulas calculating the volume ...
where G, R g, and B are constants related to the scattering contrast, structural volume, surface area, and radius of gyration. q is the magnitude of the scattering vector which is related to the Bragg spacing, d, q = 2π/d = 4π/λ sin(θ/2). λ is the wavelength and θ is the scattering angle (2θ in diffraction).