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The vinyl cation is a carbocation with the positive charge on an alkene carbon. Its empirical formula of the parent ion is C 2 H + 3.Vinyl cation are invoked as reactive intermediates in solvolysis of vinyl halides, [1] [2] as well as electrophilic addition to alkynes and allenes.
High-resolution audio (high-definition audio or HD audio) is a term for audio files with greater than 44.1 kHz sample rate or higher than 16-bit audio bit depth. It commonly refers to 96 or 192 kHz sample rates. However, 44.1 kHz/24-bit, 48 kHz/24-bit and 88.2 kHz/24-bit recordings also exist that are labeled HD audio.
An audio format is a medium for sound recording and reproduction. The term is applied to both the physical recording media and the recording formats of the audio content —in computer science it is often limited to the audio file format , but its wider use usually refers to the physical method used to store the data.
When a disc began to wear, video and audio quality would severely decline, and the disc would begin to skip. [20] Several discs suffered from a condition called "video virus", where a CED would skip a great deal due to dust particles stuck in the grooves of the disc. However, playing the disc several times would generally solve this problem. [21]
A carbocation is an ion with a positively charged carbon atom. Among the simplest examples are the methenium CH + 3, methanium CH + 5, acylium ions RCO +, and vinyl C 2 H + 3 cations. [2] Until the early 1970s, carbocations were called carbonium ions. [3]
The result of this process is an almost retail DVD quality surround sound audio track which is included in the movie release. Releases of this type are normally tagged AC3.5.1.HQ and details about what was done to the audio track as well as the video are present in the release notes accompanying the pirated movie. [17]
The perception of analog audio being demonstrably superior was also called into question by music analysts following revelations that audiophile label Mobile Fidelity Sound Lab had been covertly using Direct Stream Digital files to produce vinyl releases marketed as coming from analog master tapes, with lawyer and audiophile Randy Braun stating ...
A music download is the digital transfer of music via the Internet into a device capable of decoding and playing it, such as a personal computer, portable media player, MP3 player or smartphone. This term encompasses both legal downloads and downloads of copyrighted material without permission or legal payment.