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It can be prepared by reacting a sodium-containing base such as sodium hydroxide with iodic acid, for example: HIO 3 + NaOH → NaIO 3 + H 2 O. It can also be prepared by adding iodine to a hot, concentrated solution of sodium hydroxide or sodium carbonate: 3 I 2 + 6 NaOH → NaIO 3 + 5 NaI + 3 H 2 O
Iodic acid is a white water-soluble solid with the chemical formula HIO 3. Its robustness contrasts with the instability of chloric acid and bromic acid. Iodic acid features iodine in the oxidation state +5 and is one of the most stable oxo-acids of the halogens. When heated, samples dehydrate to give iodine pentoxide. On further heating, the ...
Ammonium iodate can be obtained by neutralising a solution of iodic acid with ammonia. [2] HIO 3 + NH 3 → NH 4 IO 3. Using its low solubility in water, it can also be precipitated from an iodate solution with an ammonium salt. 2 KIO 3 + (NH 4) 2 SO 4 → 2 NH 4 IO 3 + K 2 SO 4
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Calcium iodate, Ca(IO 3) 2, is the principal ore of iodine.It is also used as a nutritional supplement for cattle. Potassium iodate, KIO 3, like potassium iodide, has been issued as a prophylaxis against radioiodine absorption in some countries.
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In general, the salts can be prepared from preformed hypervalent iodines such as iodic acid, iodosyl sulfate or iodosyl triflate. The first such compound was synthesised in 1894, via the silver hydroxide-catalyzed coupling of two aryl iodides (the Meyer–Hartmann reaction): [19] [20] [21]
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