Search results
Results from the WOW.Com Content Network
Neopentyl alcohol can be prepared from the hydroperoxide of diisobutylene. [3] It can also be prepared by the reduction of trimethylacetic acid with lithium aluminium hydride . Neopentyl alcohol was the first described in 1891 by L. Tissier, who prepared it by reduction of a mixture of trimethyl acetic acid and trimethylacetyl chloride with ...
or neopentyl alcohol primary 2,2-Dimethylpropan-1-ol: 113.1 2-pentanol or sec-amyl alcohol or methyl (n) propyl carbinol secondary Pentan-2-ol: 118.8 3-methyl-2-butanol or sec-isoamyl alcohol or methyl isopropyl carbinol secondary 3-Methylbutan-2-ol: 113.6 3-Pentanol secondary Pentan-3-ol: 115.3 2-methyl-2-butanol or tert-amyl alcohol tertiary
This list is ordered by the number of carbon atoms in an alcohol. C1 ... Neopentyl alcohol; 2-Pentanol; 3-Methyl-2-butanol; 3-Pentanol; tert-Amyl alcohol; C6 ...
A primary alcohol is an alcohol in which the hydroxy group is bonded to a primary carbon atom. It can also be defined as a molecule containing a “–CH 2 OH” group. [1] In contrast, a secondary alcohol has a formula “–CHROH” and a tertiary alcohol has a formula “–CR 2 OH”, where “R” indicates a carbon-containing group.
Pentyl is a five-carbon alkyl group or substituent with chemical formula-C 5 H 11.It is the substituent form of the alkane pentane.. In older literature, the common non-systematic name amyl was often used for the pentyl group.
Tertiary alcohols react with strong acids to generate carbocations. The reaction is related to their dehydration, e.g. isobutylene from tert-butyl alcohol. A special kind of dehydration reaction involves triphenylmethanol and especially its amine-substituted derivatives. When treated with acid, these alcohols lose water to give stable ...
A neopentyl group attached to a generic group R. A neopentyl substituent, often symbolized by "Np", has the structure Me 3 C–CH 2 – for instance neopentyl alcohol (Me 3 CCH 2 OH or NpOH). As Np also symbolises the element neptunium (atomic number 93) one should use this abbreviation with care.
Phosphite esters with tertiary alkyl halide groups can undergo the reaction, which would be unexpected if only an S N 2 mechanism was operating. Further support for this S N 1 type mechanism comes from the use of the Arbuzov reaction in the synthesis of neopentyl halides, a class of compounds that are notoriously unreactive towards S N 2