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Printable version; Page information; Get shortened URL; Download QR code; In other projects Appearance. ... Di-tert-butyl ether chemical structure: Date: 22 April 2007:
Printable version; In other projects Wikimedia Commons; Wikidata item; Appearance. move to sidebar hide ... Di-tert-butyl ether is a tertiary ether, ...
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The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Tert-Butyl alcohol; Tert-Butyl bromide; Tert-Butyl chloride; Tert-Butyl hydroperoxide; Tert-Butyl isocyanide; Butyl PBD; Tert-Butylamine; Butylated hydroxyanisole; Butylated hydroxytoluene; 4-tert-Butylbenzaldehyde; N-tert-Butylbenzenesulfinimidoyl chloride; Para-tert-Butylbenzoic acid; 4-tert-Butylcatechol; Tert-Butyldiphenylsilyl; Tert ...
Isobutylene (or 2-methylpropene) is a hydrocarbon with the chemical formula (CH 3) 2 C=CH 2. It is a four-carbon branched alkene (olefin), one of the four isomers of butylene . It is a colorless flammable gas, and is of considerable industrial value.
The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...
The intermediate in this synthesis is di-tert-butylcyclopentadiene. This compound is conveniently prepared by alkylation of cyclobutadiene with tert-butyl bromide under phase-transfer conditions. [2] [1] Illustrative of the unusual complexes made possible with these bulky ligands is molecular iron nitrido complex (t Bu 3 C 5 H 2) 2 Fe 2 N 2. [3]
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