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Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments.
The electron transfers from pheophytin to plastoquinone (PQ), which takes 2e-(in two steps) from pheophytin, and two H + Ions from the stroma to form PQH 2. This plastoquinol is later oxidized back to PQ, releasing the 2e - to the cytochrome b 6 f complex and the two H + ions into the thylakoid lumen .
The back transfer is so favorable that it takes place in the inverted region where electron-transfer rates become slower. [1] Thus, electron transfer proceeds efficiently from the first electron acceptor to the next, creating an electron transport chain that ends when it has reached NADPH.
This process of reducing quinone is comparable to that which takes place in the bacterial reaction center. Photosystem II obtains electrons by oxidizing water in a process called photolysis. Molecular oxygen is a byproduct of this process, and it is this reaction that supplies the atmosphere with oxygen.
One of the most important null cycles takes place in the stratosphere, with the photolysis of ozone by ultraviolet photons with wavelengths less than 330 nanometers. This photolysis produces a monatomic oxygen that then reacts with the diatomic oxygen producing ozone. [2] There is no net molecular or atomic change, however.
In plants and algae, photosynthesis takes place in organelles called chloroplasts. A typical plant cell contains about 10 to 100 chloroplasts. The chloroplast is enclosed by a membrane. This membrane is composed of a phospholipid inner membrane, a phospholipid outer membrane, and an intermembrane space.
Photolysis by photosystem II oxidises water to oxygen, protons and electrons in the lumen. The transfer of electrons from photosystem II to plastoquinone during non-cyclic electron transport consumes two protons from the stroma. These are released in the lumen when the reduced plastoquinol is oxidized by the cytochrome b6f protein complex on ...
Photoexcitation is the first step in a photochemical process where the reactant is elevated to a state of higher energy, an excited state.The first law of photochemistry, known as the Grotthuss–Draper law (for chemists Theodor Grotthuss and John W. Draper), states that light must be absorbed by a chemical substance in order for a photochemical reaction to take place.