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Corrosion may occur where stale sewage generates hydrogen sulfide gas into an atmosphere containing oxygen gas and high relative humidity. There must be an underlying anaerobic aquatic habitat containing sulfates and an overlying aerobic aquatic habitat separated by a gas phase containing both oxygen and hydrogen sulfide at concentrations in excess of 2 ppm.
Sediment samples to be analyzed are first purged with argon or nitrogen gas to ensure they are anoxic. The sample is placed in a flask connected to an apparatus for trapping hydrogen sulfide gas (H 2 S). Oxygen-free water and hydrochloric acid (HCl) are added, and the sediment is stirred for one hour while argon or nitrogen gas is bubbled ...
Fuel is burned at one end to melt the dry sulfide concentrates (usually after partial roasting) which are fed through openings in the roof of the furnace. The slag floats over the heavier matte and is removed and discarded or recycled. The sulfide matte is then sent to the converter. The precise details of the process vary from one furnace to ...
Many metal and nonmetal sulfides, e.g. aluminium sulfide, phosphorus pentasulfide, silicon disulfide liberate hydrogen sulfide upon exposure to water: [28] 6 H 2 O + Al 2 S 3 → 3 H 2 S + 2 Al(OH) 3. This gas is also produced by heating sulfur with solid organic compounds and by reducing sulfurated organic compounds with hydrogen.
The residual hydrogen, methane, ethane, and some propane is used as refinery fuel gas. The hydrogen sulfide removed and recovered by the amine gas treating unit is subsequently converted to elemental sulfur in a Claus process unit or to sulfuric acid in a wet sulfuric acid process or in the conventional Contact Process.
The by-product gases mainly originate from physical and chemical gas treatment units (Selexol, Rectisol, Purisol and amine scrubbers) in refineries, natural gas processing plants and gasification or synthesis gas plants. These by-product gases may also contain hydrogen cyanide, hydrocarbons, sulfur dioxide or ammonia.
In addition to being toxic, hydrogen sulfide in the presence of water also damages piping and other equipment handling sour gas by sulfide stress cracking. Natural gas typically contains several ppm of volatile sulfur compounds, but gas from one well in Canada is known to contain 90% hydrogen sulfide and others may have H 2 S contents in the ...
Amine gas plant at a natural gas field. Amine gas treating, also known as amine scrubbing, gas sweetening and acid gas removal, refers to a group of processes that use aqueous solutions of various alkylamines (commonly referred to simply as amines) to remove hydrogen sulfide (H 2 S) and carbon dioxide (CO 2) from gases.