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  2. Fundamental resolution equation - Wikipedia

    en.wikipedia.org/wiki/Fundamental_Resolution...

    The [N 1/2 /4] term is the column factor, the [(α-1)/α] term is the thermodynamic factor, and the [k 2 '/(1+k 2 ')] term is the retention factor. The 3 factors are not completely independent, but they are very close, and can be treated as such.

  3. Arithmetico-geometric sequence - Wikipedia

    en.wikipedia.org/wiki/Arithmetico-geometric_sequence

    An arithmetico-geometric series is a sum of terms that are the elements of an arithmetico-geometric sequence. Arithmetico-geometric sequences and series arise in various applications, such as the computation of expected values in probability theory , especially in Bernoulli processes .

  4. Debye–Hückel theory - Wikipedia

    en.wikipedia.org/wiki/Debye–Hückel_theory

    An idealized representation of a solution of a 1:1 electrolyte. A description of Debye–Hückel theory includes a very detailed discussion of the assumptions and their limitations as well as the mathematical development and applications. [5] A snapshot of a 2-dimensional section of an idealized electrolyte solution is shown in the picture.

  5. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    where ln denotes the natural logarithm, is the thermodynamic equilibrium constant, and R is the ideal gas constant.This equation is exact at any one temperature and all pressures, derived from the requirement that the Gibbs free energy of reaction be stationary in a state of chemical equilibrium.

  6. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. [1]A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction.

  7. List of unsolved problems in chemistry - Wikipedia

    en.wikipedia.org/wiki/List_of_unsolved_problems...

    This article needs attention from an expert in chemistry. The specific problem is: Incomplete list. WikiProject Chemistry may be able to help recruit an expert.

  8. Runge–Kutta methods - Wikipedia

    en.wikipedia.org/wiki/Runge–Kutta_methods

    In numerical analysis, the Runge–Kutta methods (English: / ˈ r ʊ ŋ ə ˈ k ʊ t ɑː / ⓘ RUUNG-ə-KUUT-tah [1]) are a family of implicit and explicit iterative methods, which include the Euler method, used in temporal discretization for the approximate solutions of simultaneous nonlinear equations. [2]

  9. Direct methods (crystallography) - Wikipedia

    en.wikipedia.org/wiki/Direct_methods...

    In crystallography, direct methods are a family of methods for estimating the phases of the Fourier transform of the scattering density from the corresponding magnitudes. . The methods generally exploit constraints or statistical correlations between the phases of different Fourier components that result from the fact that the scattering density must be a positive real nu