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4.3.1 One oxygen in ring. 4.3.2 Two oxygens in ring. 4.4 Five atoms in ring. Toggle the table of contents. C 3 H 6 O 2. 11 languages.
Cyclohexane-1,2,3,4,5,6-hexol is a family of chemical compounds with formula C 6 H 12 O 6, whose molecule consists of a ring of six carbon atoms, each bound to one hydrogen atom and one hydroxyl group (–OH). There are nine stereoisomers, that differ by the position of the hydroxyl groups relative to the mean plane of the ring.
Prismane, like the other proposed structures for benzene, is still often cited in the literature, because it is part of the historical struggle toward understanding the mesomeric structures and resonance of benzene. Some computational chemists still research the differences between the possible isomers of C 6 H 6. [4]
The most common one in nature (myo-inositol) has the hydroxyls on carbons 1, 2, 3 and 5 on the same side of that plane, and can therefore be called cis-1,2,3,5-trans-4,6-cyclohexanehexol. And each of these cis - trans isomers can possibly have stable "chair" or "boat" conformations (although the barriers between these are significantly lower ...
Structural isomers have a different ordering of bonds and/or different bond connectivity from one another, as in the case of hexane and its four other isomeric forms (2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, and 2,3-dimethylbutane).
[2] [3] The term metamer was formerly used for the same concept. [4] For example, butanol H 3 C−(CH 2) 3 −OH, methyl propyl ether H 3 C−(CH 2) 2 −O−CH 3, and diethyl ether (H 3 CCH 2 −) 2 O have the same molecular formula C 4 H 10 O but are three distinct structural isomers. The concept applies also to polyatomic ions with the same ...
For ML a 3 L b 3, two isomers are possible - a facial isomer (fac) in which each set of three identical ligands occupies one face of the octahedron surrounding the metal atom, so that any two of these three ligands are mutually cis, and a meridional isomer (mer) in which each set of three identical ligands occupies a plane passing through the metal atom.
Le Bel-van't Hoff rule states that for a structure with n asymmetric carbon atoms, there is a maximum of 2 n different stereoisomers possible. As an example, D-glucose is an aldohexose and has the formula C 6 H 12 O 6. Four of its six carbon atoms are stereogenic, which means D-glucose is one of 2 4 =16 possible stereoisomers. [20] [21]