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The λ 5-iodanes such as the Dess-Martin periodinane have square pyramidal geometry with 4 heteroatoms in basal positions and one apical phenyl group. [1]Iodoxybenzene or iodylbenzene, C 6 H 5 IO 2, is a known oxidizing agent.
The iodine clock reaction is a classical chemical clock demonstration experiment to display chemical kinetics in action; it was discovered by Hans Heinrich Landolt in 1886. [1] The iodine clock reaction exists in several variations, which each involve iodine species (iodide ion, free iodine, or iodate ion) and redox reagents in the presence of ...
The iodine content and thus the active chlorine content can be determined with iodometry. [3] The determination of arsenic(V) compounds is the reverse of the standardization of iodine solution with sodium arsenite, where a known and excess amount of iodide is added to the sample: As 2 O 5 + 4 H + + 4 I − ⇌ As 2 O 3 + 2 I 2 + 2 H 2 O
Iodine trichloride, which exists in the solid state as the planar dimer I 2 Cl 6, is a bright yellow solid, synthesised by reacting iodine with liquid chlorine at −80 °C; caution is necessary during purification because it easily dissociates to iodine monochloride and chlorine and hence can act as a strong chlorinating agent.
Reagents are "substances or compounds that are added to a system in order to bring about a chemical reaction or are added to see if a reaction occurs." [1] Some reagents are just a single element. However, most processes require reagents made of chemical compounds. Some of the most common ones used widely for specific reactive functions are ...
Bis(pyridine)iodonium(I) tetrafluoroborate or Barluenga's reagent, named after José Barluenga, [1] is a mild iodinating reagent. Commercially available, it may be prepared by reacting iodine with pyridine in the presence of silver tetrafluoroborate supported on silica gel .
The related diacetate, C 6 H 5 I(O 2 CCH 3) 2, illustrates the ability of iodine(III) to adopt a T-shaped geometry without multiple bonds. [8] Theoretical studies show that the bonding between the iodine and oxygen atoms in iodosobenzene represents a single dative I-O sigma bond, confirming the absence of the double I=O bond.
A compound with iodine(V) would be a λ 5 ‑iodane, and a hypothetical iodine(VII)‑containing compound would be a λ 7 ‑iodane. Organyl-iodine ethers, a kind of λ 3 ‑iodane, are sometimes called organic hypoiodites. Alternatively, the hypervalent iodines can be classified using neutral electron counting.