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The Born–Haber cycle is an approach to analyze reaction energies. It was named after two German scientists, Max Born and Fritz Haber , who developed it in 1919. [ 1 ] [ 2 ] [ 3 ] It was also independently formulated by Kazimierz Fajans [ 4 ] and published concurrently in the same journal. [ 1 ]
Alternation of generations – Beta oxidation – Bioelectricity – Biological pest control – Biological rhythm – Bipolar disorder – Cardiopulmonary resuscitation – Calvin–Benson cycle – Cell cycle – Chronobiology – Citric acid cycle – Circadian rhythm – Clinical depression – Digestion – Ecology – Feedback – Infradian rhythm - Life cycle – List of biochemistry ...
For example, Na–Cl and Mg–O interactions have a few percent covalency, while Si–O bonds are usually ~50% ionic and ~50% covalent. Pauling estimated that an electronegativity difference of 1.7 (on the Pauling scale ) corresponds to 50% ionic character, so that a difference greater than 1.7 corresponds to a bond which is predominantly ionic.
In these cases the polarization energy E pol associated with ions on polar lattice sites may be included in the Born–Haber cycle. As an example, one may consider the case of iron-pyrite FeS 2 . It has been shown that neglect of polarization led to a 15% difference between theory and experiment in the case of FeS 2 , whereas including it ...
In some reactions between highly reactive metals (usually from Group 1 or Group 2) and highly electronegative halogen gases, or water, the atoms can be ionized by electron transfer, [16] a process thermodynamically understood using the Born–Haber cycle. [17] Salts are formed by salt-forming reactions. A base and an acid, e.g., NH 3 + HCl → ...
Born–Haber cycle – Max Born and Fritz Haber; Born–Oppenheimer approximation – Max Born and Robert Oppenheimer; Borodin–Hunsdiecker reaction – Alexander Borodin, Hienz Hunsdiecker, and Clare Hunsdiecker (née Dieckmann) Borrmann effect (a.k.a. Borrmann–Campbell effect) – Gerhard Borrman (and Herbert N. Campbell) Bortle scale ...
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Haber, along with Max Born, proposed the Born–Haber cycle as a method for evaluating the lattice energy of an ionic solid. Haber has also been described as the "father of chemical warfare " for his work developing and deploying chlorine and other poisonous gases during World War I.