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2. Levich equation - Wikipedia

   en.wikipedia.org/wiki/Levich_equation

   The Levich equation is written as: = where I L is the Levich current (A), n is the number of moles of electrons transferred in the half reaction (number), F is the Faraday constant (C/mol), A is the electrode area (cm 2), D is the diffusion coefficient (see Fick's law of diffusion) (cm 2 /s), ω is the angular rotation rate of the electrode (rad/s), ν is the kinematic viscosity (cm 2 /s), C ...

3. Rotating disk electrode - Wikipedia

   en.wikipedia.org/wiki/Rotating_disk_electrode

   An RDE cannot be used to observe the behavior of the electrode reaction products, since they are continually swept away from the electrode. However, the rotating ring-disk electrode is well suited to investigate this further reactivity. The peak current in a cyclic voltammogram for an RDE is a plateau like region, governed by the Levich ...

4. Koutecký–Levich equation - Wikipedia

   en.wikipedia.org/wiki/Koutecký–Levich_equation

   The Koutecký–Levich equation models the measured electric current at an electrode from an electrochemical reaction in relation to the kinetic activity and the mass transport of reactants. A visualization of the Koutecký–Levich equation. The graph shows the measured current as a function of the mass transport current for given kinetic current.

5. Rotating ring-disk electrode - Wikipedia

   en.wikipedia.org/wiki/Rotating_ring-disk_electrode

   The difference between a rotating ring-disk electrode and a rotating disk electrode is the addition of a second working electrode in the form of a ring around the central disk of the first working electrode. To operate such an electrode, it is necessary to use a potentiostat, such as a bipotentiostat, capable of controlling a four-electrode ...

6. Levich constant - Wikipedia

   en.wikipedia.org/wiki/Levich_Constant

   A Levich constant (B) is often used in order to simplify the Levich equation. [1] Furthermore, B is readily extracted from rotating disk electrode experimental data.. The B can be defined as: [2]

7. Marcus theory - Wikipedia

   en.wikipedia.org/wiki/Marcus_theory

   In outer sphere redox reactions no bonds are formed or broken; only an electron transfer (ET) takes place. A quite simple example is the Fe 2+ /Fe 3+ redox reaction, the self exchange reaction which is known to be always occurring in an aqueous solution containing the aquo complexes [Fe(H 2 O) 6] 2+ and [Fe(H 2 O)6] 3+.