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Thermal decomposition of magnesium nitride gives magnesium and nitrogen gas (at 700-1500 °C). At high pressures, the stability and formation of new nitrogen-rich nitrides (N/Mg ratio equal or greater to one) were suggested and later discovered. [4] [5] [6] These include the Mg 2 N 4 and MgN 4 solids which both become thermodynamically stable ...
A method for nitrogen fixation was first described by Henry Cavendish in 1784 using electric arcs reacting nitrogen and oxygen in air. This method was implemented in the Birkeland–Eyde process of 1903. [73] The fixation of nitrogen by lightning is a very similar natural occurring process.
While the mechanism for nitrogen fixation prior to the Janus E 4 complex is generally agreed upon, there are currently two hypotheses for the exact pathway in the second half of the mechanism: the "distal" and the "alternating" pathway. [9] [24] [25] In the distal pathway, the terminal nitrogen is hydrogenated first, releases ammonia, then the ...
The creation of sparks from metals is based on the pyrophoricity of small metal particles, and pyrophoric alloys are made for this purpose. [2] Practical applications include the sparking mechanisms in lighters and various toys, using ferrocerium; starting fires without matches, using a firesteel; the flintlock mechanism in firearms; and spark testing ferrous metals.
Abiological nitrogen fixation describes chemical processes that fix (react with) N 2, usually with the goal of generating ammonia. The dominant technology for abiological nitrogen fixation is the Haber process, which uses iron-based heterogeneous catalysts and H 2 to convert N 2 to NH 3. This article focuses on homogeneous (soluble) catalysts ...
Nitrogen assimilation is the formation of organic nitrogen compounds like amino acids from inorganic nitrogen compounds present in the environment. Organisms like plants, fungi and certain bacteria that can fix nitrogen gas (N 2) depend on the ability to assimilate nitrate or ammonia for their needs. Other organisms, like animals, depend ...
The overall process is called nitrogen fixation. Intense effort has been directed toward understanding the mechanism of biological nitrogen fixation. The scientific interest in this problem is motivated by the unusual structure of the active site of the enzyme, which consists of an Fe 7 MoS 9 ensemble. [168]
Repeating the same reaction but replacing Dur (2,3,5,6-tetramethyl-phenyl) group by a bulkier Tip (2,4,6-triisopropylphenyl) group resulted in a very different result: after the dinitrogen was coordinated by the first borylene molecule, the second coordination by another borylene molecule was considerably hindered by steric repulsion in the ...