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In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram.It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
[4] [5] [6] The CALPHAD approach is based on the fact that a phase diagram is a manifestation of the equilibrium thermodynamic properties of the system, which are the sum of the properties of the individual phases. [7] It is thus possible to calculate a phase diagram by first assessing the thermodynamic properties of all the phases in a system.
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
Consider the reaction A ⇌ 2 B + 3 C. Suppose an infinitesimal amount of the reactant A changes into B and C. This requires that all three mole numbers change according to the stoichiometry of the reaction, but they will not change by the same amounts.
Conversely, a phase reversal or phase inversion implies a 180-degree phase shift. [ 2 ] When the phase difference φ ( t ) {\displaystyle \varphi (t)} is a quarter of turn (a right angle, +90° = π/2 or −90° = 270° = −π/2 = 3π/2 ), sinusoidal signals are sometimes said to be in quadrature , e.g., in-phase and quadrature components of a ...
The family returned to find their house and garden covered in a layer of ash. They spent days cleaning the house; washing their clothes, bedding and rugs; and throwing away pillows that had ...
Different such amounts can even generate different hyperplanes, all sharing the same algebraic stoichiometry. In accord with the principles of chemical kinetics and thermodynamic equilibrium , every chemical reaction is reversible , at least to some degree, so that each equilibrium point must be an interior point of the simplex.