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The spectral resolution of a spectrograph, or, more generally, of a frequency spectrum, is a measure of its ability to resolve features in the electromagnetic spectrum.It is usually denoted by , and is closely related to the resolving power of the spectrograph, defined as =, where is the smallest difference in wavelengths that can be distinguished at a wavelength of .
Mathematically, for the spectral power distribution of a radiant exitance or irradiance one may write: =where M(λ) is the spectral irradiance (or exitance) of the light (SI units: W/m 2 = kg·m −1 ·s −3); Φ is the radiant flux of the source (SI unit: watt, W); A is the area over which the radiant flux is integrated (SI unit: square meter, m 2); and λ is the wavelength (SI unit: meter, m).
The Planck relation [1] [2] [3] (referred to as Planck's energy–frequency relation, [4] the Planck–Einstein relation, [5] Planck equation, [6] and Planck formula, [7] though the latter might also refer to Planck's law [8] [9]) is a fundamental equation in quantum mechanics which states that the energy E of a photon, known as photon energy, is proportional to its frequency ν: =.
To calculate the energy in the box in this way, we need to evaluate how many photon states there are in a given energy range. If we write the total number of single photon states with energies between ε and ε + dε as g ( ε ) dε , where g ( ε ) is the density of states (which is evaluated below), then the total energy is given by
The rate at which EM energy is detected by the detector is measured. This measured rate is then divided by Δλ to obtain the detected power per square metre per unit wavelength range. Spectral flux density is often used as the quantity on the y-axis of a graph representing the spectrum of a light-source, such as a star.
σ λ is their absorption cross-section at wavelength λ (units: area) B λ (T) is the Planck function for temperature T and wavelength λ (units: power/area/solid angle/wavelength - e.g. watts/cm 2 /sr/cm) I λ is the spectral intensity of the radiation entering the increment ds with the same units as B λ (T)
To find the value of the energy spectral density ¯ at frequency , one could insert between the transmission line and the resistor a bandpass filter which passes only a narrow range of frequencies (, say) near the frequency of interest and then measure the total energy () dissipated across the resistor.
In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.