Search results
Results from the WOW.Com Content Network
The first type, shown on the right and left of the diagram, uses an electrolyte of sodium chloride solution, a graphite anode (A), and a mercury cathode (M). The other type of cell, shown in the center of the diagram, uses an electrolyte of sodium hydroxide solution, a mercury anode (M), and an iron cathode (D). The mercury electrode is common ...
The most common chloralkali process involves the electrolysis of aqueous sodium chloride (a brine) in a membrane cell. A membrane, such as Nafion, Flemion or Aciplex, is used to prevent the reaction between the chlorine and hydroxide ions. Basic membrane cell used in the electrolysis of brine.
Electrolysis of iron can eliminate direct emissions and further reduce emissions if the electricity is created from green energy. The small-scale electrolysis of iron has been successfully reported by dissolving it in molten oxide salts and using a platinum anode. [53] Oxygen anions form oxygen gas and electrons at the anode.
Chlorine can also be produced by the electrolysis of a solution of potassium chloride, in which case the co-products are hydrogen and caustic potash (potassium hydroxide). There are three industrial methods for the extraction of chlorine by electrolysis of chloride solutions, all proceeding according to the following equations:
Before Dow entered the bromine business, brine was evaporated by heating with wood scraps and then crystallized sodium chloride was removed. An oxidizing agent was added, and bromine was formed in the solution. Then bromine was distilled. This was a very complicated and costly process.
In the chloralkali process (electrolysis of brine) a water/sodium chloride mixture is only half the electrolysis of water since the chloride ions are oxidized to chlorine rather than water being oxidized to oxygen. Thermodynamically, this would not be expected since the oxidation potential of the chloride ion is less than that of water, but the ...
Electrochemical processes, such as electrolysis of brine without a membrane operating to form hypochlorite, will also produce bromate when bromide ion is present in the brine solution. Photoactivation (sunlight exposure) will encourage liquid or gaseous bromine to generate bromate in bromide-containing water.
Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water.In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for brining foods) up to about 26% (a typical saturated solution, depending on temperature).