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The thiocarbonate moiety can be functionalized at the R-group for end group analysis. The end group is a result of the propagation of chain-transfer agents during the free-radical polymerization process. The end groups can subsequently be modified by the reaction of the thiocarbonylthio compounds with nucleophiles and ionic reducing agents. [11]
Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
The numbers 200-900 would be confused easily with 22 to 29 if they were used in chemistry. khīlioi = 1000, diskhīlioi = 2000, triskhīlioi = 3000, etc. 13 to 19 are formed by starting with the Greek word for the number of ones, followed by και (the Greek word for 'and'), followed by δέκα (the Greek word for 'ten').
The subunits that make up each of these structures are identified, i.e., the largest divalent groups that can be named using IUPAC nomenclature of organic chemistry. In the example, the two-carbon ethylidene unit is longer than two separate one-carbon methanediyl units. Figure 1. The order of subunit precedence.
Some telomerizations proceed by radical pathways, many do not. A generic equation is: + where M is the monomer, and A and B are the end groups, and n is the degree of polymerization. One example is the coupled dimerization and hydroesterification of buta-1,3-diene.
The simplest form of a group-contribution method is the determination of a component property by summing up the group contributions : [] = +.This simple form assumes that the property (normal boiling point in the example) is strictly linearly dependent on the number of groups, and additionally no interaction between groups and molecules are assumed.
A telechelic polymer or oligomer is a prepolymer capable of entering into further polymerization or other reactions through its reactive end-groups. [1] It can be used for example to synthesize block copolymers. By definition, a telechelic polymer is a di-end-functional polymer where both ends possess the same functionality. [2]
In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.