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Lithium bromide was used as a sedative beginning in the early 1900s, but it fell into disfavor in the 1940s as newer sedatives became available and when some heart patients died after using the salt substitute lithium chloride. [11] Like lithium carbonate and lithium chloride, it was used as treatment for bipolar disorder.
Lithium borohydride (LiBH 4) is a borohydride and known in organic synthesis as a reducing agent for esters. Although less common than the related sodium borohydride , the lithium salt offers some advantages, being a stronger reducing agent and highly soluble in ethers, whilst remaining safer to handle than lithium aluminium hydride .
Expressing resonance when drawing Lewis structures may be done either by drawing each of the possible resonance forms and placing double-headed arrows between them or by using dashed lines to represent the partial bonds (although the latter is a good representation of the resonance hybrid which is not, formally speaking, a Lewis structure).
Lithium hydroxide is another important compound that is used in air purification systems, as well as in the production of lithium greases and lubricants. Lithium chloride is used as a desiccant and in the production of lithium metal, while lithium sulfate is used in the production of fertilizers and as a reagent in chemical reactions
Lithium metaborate is a chemical compound of lithium, boron, and oxygen with elemental formula LiBO 2. It is often encountered as a hydrate , LiBO 2 · n H 2 O , where n is usually 2 or 4. However, these formulas do not describe the actual structure of the solids.
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The chemistry of lithium shows several differences from that of the rest of the group as the small Li + cation polarises anions and gives its compounds a more covalent character. [5] Lithium and magnesium have a diagonal relationship due to their similar atomic radii, [5] so that they show some similarities.
The lithium bromide forms a complex with the methyllithium. Most commercially available methyllithium consists of this complex. "Low-halide" methyllithium is prepared from methyl chloride. [1] Lithium chloride precipitates from the diethyl ether since it does not form a strong complex with methyllithium. The filtrate consists of fairly pure ...