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Boyle's law demonstrations. The law itself can be stated as follows: For a fixed mass of an ideal gas kept at a fixed temperature, pressure and volume are inversely proportional. [2] Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa ...
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
Real gases are non-ideal gases whose molecules occupy space and have interactions; consequently, they do not adhere to the ideal gas law. To understand the behaviour of real gases, the following must be taken into account: compressibility effects; variable specific heat capacity; van der Waals forces; non-equilibrium thermodynamic effects;
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Boyle's_Law_Demonstrations.webm (WebM audio/video file, VP8/Vorbis, length 1 min 32 s, 640 × 480 pixels, 326 kbps overall, file size: 3.57 MB) This is a file from the Wikimedia Commons . Information from its description page there is shown below.
The Boyle temperature, named after Robert Boyle, is formally defined as the temperature for which the second virial coefficient, (), becomes zero. It is at this temperature that the attractive forces and the repulsive forces acting on the gas particles balance out
Using such tools, some quantitative force laws were discovered: that the force of gravity is proportional to volume for objects of constant density (widely exploited for millennia to define standard weights); Archimedes' principle for buoyancy; Archimedes' analysis of the lever; Boyle's law for gas pressure; and Hooke's law for springs.
These three gas laws in combination with Avogadro's law can be generalized by the ideal gas law. Gay-Lussac used the formula acquired from ΔV/V = αΔT to define the rate of expansion α for gases. For air, he found a relative expansion ΔV/V = 37.50% and obtained a value of α = 37.50%/100 °C = 1/266.66 °C which indicated that the value of ...