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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
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To use potentiometric (e.m.f.) measurements in monitoring the + concentration in place of readings, one can trivially set [+] = and apply the same equations as above, where is the offset correction /, and is a slope correction / (1/59.2 pH units/mV at 25°C), such that replaces .
This equation is the equation of a straight line for as a function of pH with a slope of () volt (pH has no units). This equation predicts lower E h {\displaystyle E_{h}} at higher pH values. This is observed for the reduction of O 2 into H 2 O, or OH − , and for reduction of H + into H 2 .
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PH 3 (g) -0.111 3 [10] C CO 2 (g) + 2 H + + 2 e −: ⇌ HCOOH(aq) -0.11 2 Se Se(s) + 2 H + + 2 e −: ⇌ H 2 Se (g) -0.11 2 [6]: 790 C CO 2 (g) + 2 H + + 2 e −: ⇌ CO(g) + H 2 O-0.11 2 Sn: α-SnO(s) + 2 H + + 2 e −: ⇌: Sn(s) + H 2 O-0.104: 2 [6]: 788 Cu Cu(NH 3) + 2 + e −: ⇌ Cu(s) + 2 NH 3 (aq) -0.1 1 [13] Nb: Nb 2 O 5 (s) + 10 H ...
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The pH range is commonly given as zero to 14, but a pH value can be less than 0 for very concentrated strong acids or greater than 14 for very concentrated strong bases. [2] The pH scale is traceable to a set of standard solutions whose pH is established by international agreement. [3]