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Measuring contact angles for pendant drops is much more complicated than for sessile drops due to the inherent unstable nature of inverted drops. This complexity is further amplified when one attempts to incline the surface. Experimental apparatus to measure pendant drop contact angles on inclined substrates has been developed recently. [20]
The most common way to measure surface energy is through contact angle experiments. [1] In this method, the contact angle of the surface is measured with several liquids, usually water and diiodomethane. Based on the contact angle results and knowing the surface tension of the liquids, the surface energy can be calculated. In practice, this ...
The captive bubble method is a method for measuring the contact angle between a liquid and a solid, by using drop shape analysis. [1] In this method, a bubble of air is injected beneath a solid, the surface of which is located in the liquid, instead of placing a drop on the solid as in the case of the sessile drop technique.
This type of measurement is referred to as a static contact angle measurement. [3] The contact angle is affected not only by the surface chemistry but also by the surface roughness. The Young equation, which is the basis for the contact angle, assumes a homogeneous surface with no surface roughness.
The formation of menisci is commonly used in surface science to measure contact angles and surface tension. In a contact angle measurement, the shape of the menisci is measured with a balance or optically with a digital camera. In a surface tension measurement, the measurement probe has a contact angle of zero and the surface tension can be ...
Wettability is a measure of how well a liquid spreads and how complete the contact of the liquid is across the surface of a solid interface. A small contact angle indicates good wettability, while a large contact angle indicates poor wettability.
This means that although the difference between the liquid–solid and solid–air surface tension, γ ls − γ sa, is difficult to measure directly, it can be inferred from the liquid–air surface tension, γ la, and the equilibrium contact angle, θ, which is a function of the easily measurable advancing and receding contact angles (see ...
An ideal solid surface is flat, rigid, perfectly smooth, and chemically homogeneous, and has zero contact angle hysteresis. Zero hysteresis implies the advancing and receding contact angles are equal. Figure 1: Contact angle for a liquid droplet on a solid surface. In other words, only one thermodynamically stable contact angle exists. When a ...
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