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The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
Up to 99.63 °C (the boiling point of water at 0.1 MPa), at this pressure water exists as a liquid. Above that, it exists as water vapor. Note that the boiling point of 100.0 °C is at a pressure of 0.101325 MPa (1 atm), which is the average atmospheric pressure.
The CRC Handbook of Chemistry and Physics is a comprehensive one-volume reference resource for science research. First published in 1914, it is currently (as of 2024) in its 105th edition, published in 2024. It is known colloquially among chemists as the "Rubber Bible", as CRC originally stood for "Chemical Rubber Company". [2]
Log 10 of ethanol vapor pressure vs. temperature. ... Density relative to 4 °C water ... Data obtained from CRC Handbook of Chemistry ...
Here is a similar formula from the 67th edition of the CRC handbook. Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures: log 10 (P) = −(0.05223)a/T + b, where P is in mmHg, T is in kelvins, a = 38324, and b = 8.8017.
David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition, online version. CRC Press. Boca Raton, Florida, 2003; Section 4, Properties of the Elements and Inorganic Compounds; Vapor Pressure of the Metallic Elements The equations reproduce the observed pressures to an accuracy of ±5% or better. Coefficients from this source:
Table data obtained from CRC Handbook of Chemistry and Physics, 44th ed. ... Temperature dependence of ethylene glycol vapor pressure. ... % by mole water liquid ...
The vapor pressure of water is the pressure exerted by molecules of water vapor in gaseous ... a good reference manual (e.g.: CRC Handbook of Chemistry and Physics ...