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Chromic acid is capable of oxidizing many kinds of organic compounds and many variations on this reagent have been developed: Chromic acid in aqueous sulfuric acid and acetone is known as the Jones reagent, which will oxidize primary and secondary alcohols to carboxylic acids and ketones respectively, while rarely affecting unsaturated bonds. [12]
For aluminum, the chromate conversion bath can be simply a solution of chromic acid. The process is rapid (1–5 min), requires a single ambient temperature process tank and associated rinse, and is relatively trouble free. [2] As of 1995, Henkel's Alodine 1200s commercial formula for aluminum consisted of 50-60% chromic anhydride CrO
Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO 3. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. [6] This compound is a dark-purple solid under anhydrous conditions and bright orange when wet. The substance dissolves in water ...
Chromyl chloride can be prepared by the reaction of potassium chromate or potassium dichromate with hydrogen chloride in the presence of concentrated sulfuric acid, followed by distillation. [3] [4] K 2 Cr 2 O 7 + 6 HCl → 2 CrO 2 Cl 2 + 2 KCl + 3 H 2 O. The sulfuric acid serves as a dehydration agent.
The composition of CCA products is usually described in terms of the mass percentages of chromium trioxide or "chromic acid" CrO 3, arsenic pentoxide As 2 O 5, and copper(II) oxide CuO. [3] The preservative is applied as a water-based mixture containing 0.6–6.0% (by weight) of chromic acid, copper oxide, and arsenic acid (USDA, 1980), with pH ...
It is obtained on a vast scale by roasting chromium ores in air in the presence of sodium carbonate: 2Cr 2 O 3 + 4 Na 2 CO 3 + 3 O 2 → 4 Na 2 CrO 4 + 4 CO 2. This process converts the chromium into a water-extractable form, leaving behind iron oxides.
Lead(II) chromate can be produced by treating sodium chromate with lead salts such as lead(II) nitrate or by combining lead(II) oxide with chromic acid. Related lead sulfochromate pigments are produced by the replacement of some chromate by sulfate, resulting in a mixed lead-chromate-sulfate compositions Pb(CrO 4) 1−x (SO 4) x. This ...
Alternatively, sodium sulfate is or was formed in the production of lithium carbonate, chelating agents, resorcinol, ascorbic acid, silica pigments, nitric acid, and phenol. [ 17 ] Bulk sodium sulfate is usually purified via the decahydrate form, since the anhydrous form tends to attract iron compounds and organic compounds .