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The instrument detection limit (IDL) is the analyte concentration that is required to produce a signal greater than three times the standard deviation of the noise level. This may be practically measured by analyzing 8 or more standards at the estimated IDL then calculating the standard deviation from the measured concentrations of those standards.
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
Correction factor versus sample size n.. When the random variable is normally distributed, a minor correction exists to eliminate the bias.To derive the correction, note that for normally distributed X, Cochran's theorem implies that () / has a chi square distribution with degrees of freedom and thus its square root, / has a chi distribution with degrees of freedom.
In probability theory, a log-normal (or lognormal) distribution is a continuous probability distribution of a random variable whose logarithm is normally distributed.Thus, if the random variable X is log-normally distributed, then Y = ln(X) has a normal distribution.
In statistics, deviance is a goodness-of-fit statistic for a statistical model; it is often used for statistical hypothesis testing.It is a generalization of the idea of using the sum of squares of residuals (SSR) in ordinary least squares to cases where model-fitting is achieved by maximum likelihood.
The sample extrema can be used for a simple normality test, specifically of kurtosis: one computes the t-statistic of the sample maximum and minimum (subtracts sample mean and divides by the sample standard deviation), and if they are unusually large for the sample size (as per the three sigma rule and table therein, or more precisely a Student ...
The sample size is an important feature of any empirical study in which the goal is to make inferences about a population from a sample. In practice, the sample size used in a study is usually determined based on the cost, time, or convenience of collecting the data, and the need for it to offer sufficient statistical power. In complex studies ...
In mathematics and statistics, deviation serves as a measure to quantify the disparity between an observed value of a variable and another designated value, frequently the mean of that variable. Deviations with respect to the sample mean and the population mean (or "true value") are called errors and residuals, respectively.