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For K′ 3 there are three different dissociation constants — there are only three possibilities for which pocket is filled last (I, II or III) — and one state (I–II–III). Even when the microscopic dissociation constant is the same for each individual binding event, the macroscopic outcome (K′ 1, K′ 2 and K′ 3) is not equal. This ...
The two micro-constants represent deprotonation either at sulphur or at nitrogen, and the macro-constant sum here is the acid dissociation constant = + (+). [65] Spermine Similarly, a base such as spermine has more than one site where protonation can occur.
K a is variously named a dissociation constant, [3] an acid ionization constant, [2]: 668 an acidity constant [1] or an ionization constant. [2]: 708 It serves as an indicator of the acid strength: stronger acids have a higher K a value (and a lower pK a value).
In this equation, the base (B) and the extremely strong base (the conjugate base OH −) compete for the proton. [6] As a result, bases that react with water have relatively small equilibrium constant values. [6] The base is weaker when it has a lower equilibrium constant value. [3]
With pOH obtained from the pOH formula given above, the pH of the base can then be calculated from =, where pK w = 14.00. A weak base persists in chemical equilibrium in much the same way as a weak acid does, with a base dissociation constant (K b) indicating the strength of the base. For example, when ammonia is put in water, the following ...
Acid strength is the tendency of an acid, symbolised by the chemical formula, to dissociate into a proton, +, and an anion, .The dissociation or ionization of a strong acid in solution is effectively complete, except in its most concentrated solutions.
Base; Buffer solutions; Dissociation constant; Donor number; ... As the name suggests, a non-nucleophilic base is a sterically hindered organic base that is a poor ...
where log denotes a logarithm to base 10 or common logarithm, and K diss is a stepwise acid dissociation constant. For bases, the base association constant, pK b is used. For any given acid or base the two constants are related by pK a + pK b = pK w, so pK a can always be used in calculations.