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In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
The Joule expansion (a subset of free expansion) is an irreversible process in thermodynamics in which a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being evacuated. The partition between the two parts of the container is then opened, and the gas fills the ...
The Joule effect (during Joule expansion), the temperature change of a gas (usually cooling) when it is allowed to expand freely. The Joule–Thomson effect, the temperature change of a gas when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
This temperature change is known as the Joule–Thomson effect, and is exploited in the liquefaction of gases. Inversion temperature depends on the nature of the gas. For a van der Waals gas we can calculate the enthalpy using statistical mechanics as
An expansion valve is a valve used for different purposes: Steam engines. A valve used to control the expansion of steam: ... Joule-Thomson cooler; heat pump;
The Hampson–Linde cycle differs from the Siemens cycle only in the expansion step. Whereas the Siemens cycle has the gas do external work to reduce its temperature, the Hampson–Linde cycle relies solely on the Joule–Thomson effect ; this has the advantage that the cold side of the cooling apparatus needs no moving parts.
Unrestrained expansion of fluids; Spontaneous chemical reactions; Spontaneous mixing of matter of varying composition/states; A Joule expansion is an example of classical thermodynamics, as it is easy to work out the resulting increase in entropy. It occurs where a volume of gas is kept in one side of a thermally isolated container (via a small ...
In 1895, William Hampson in England [3] and Carl von Linde in Germany [4] independently developed and patented the Hampson–Linde cycle to liquefy air using the Joule–Thomson expansion process and regenerative cooling. [5] On 10 May 1898, James Dewar used regenerative cooling to become the first to statically liquefy hydrogen.