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In thermodynamics and chemical engineering, the vapor–liquid equilibrium (VLE) describes the distribution of a chemical species between the vapor phase and a liquid phase. The concentration of a vapor in contact with its liquid, especially at equilibrium , is often expressed in terms of vapor pressure , which will be a partial pressure (a ...
A hand boiler or (less commonly) love meter is a glass sculpture used as an experimental tool to demonstrate vapour-liquid equilibrium, or as a collector's item to whimsically "measure love." It consists of a lower bulb containing a volatile liquid and a mixture of gases that is connected usually by a twisting glass tube that connects to an ...
By adding a correction factor, known as the activity (, the activity of the i th component) to the liquid phase fraction of a liquid mixture, some of the effects of the real solution can be accounted for. The activity of a real chemical is a function of the thermodynamic state of the system, i.e. temperature and pressure.
Using mass and enthalpy balances in addition to vapor-liquid equilibrium data and enthalpy-concentration data, operating lines can be constructed using the Ponchon–Savarit method. [ 5 ] If the mixture can form an azeotrope , its vapor-liquid equilibrium line will cross the x = y line, preventing further separation no matter the number of ...
About 50 datasets of computer experiment data for the vapor–liquid equilibrium have been published to date. [21] Furthermore, more than 35,000 data points at homogeneous fluid states have been published over the years and recently been compiled and assessed for outliers in an open access database.
The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...
Vapor pressure [a] or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate.
The change in vapor pressure can be attributed to changes in the Laplace pressure. When the Laplace pressure rises in a droplet, the droplet tends to evaporate more easily. When applying the Kelvin equation, two cases must be distinguished: A drop of liquid in its own vapor will result in a convex liquid surface, and a bubble of vapor in a ...