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Dilithium acetylide is an organometallic compound with the formula Li 2 C 2. It is typically derived by double deprotonation of acetylene. X-ray crystallography confirms the presence of C≡C subunits attached to lithium, resulting in a polymeric structure. [ 3 ]
Barium carbide can be synthesized as an impure compound by reducing barium carbonate powder with metallic magnesium in the presence of carbon. [3] Barium carbide can also be made by reducing carbon dioxide with hot barium metal at 600°C. [4] These methods are used because of their high yield, and because the carbide is used to make acetylene.
It consists of Cu + cations and acetylide anions − C≡C −, with the triple bond between the two carbon atoms. Although never characterized by X-ray crystallography, the material has been claimed at least since 1856. [2] One form is claimed to be a monohydrate with formula Cu 2 C 2 ·H 2 O. Copper(I) acetylide is a reddish-brown explosive ...
When both hydrogens of acetylene are replaced by metals, the compound can also be called carbide, e.g. calcium carbide Ca 2+ [− C≡C −], which is calcium acetylide. When only one hydrogen atom is replaced, the anion may be called hydrogen acetylide or the prefix mono - may be attached to the metal, as in monosodium acetylide or sodium ...
Silver acetylide is an inorganic chemical compound with the formula Ag 2 C 2, a metal acetylide. The compound can be regarded as a silver salt of the weak acid , acetylene . The salt's anion consists of two carbon atoms linked by a triple bond , thus, its structure is [Ag + ] 2 [ − C≡C − ] .
Strontium carbide (also more precisely known as strontium acetylide or strontium dicarbide) is a salt with chemical formula SrC 2. It was first synthesized by Moissan in 1894. [1] Strontium carbide can be formed in an electric arc furnace from strontium carbonate and a reductant, such as a reducing sugar [1] [2] or magnesium metal. [3]
The carbonaceous material in an archeological sample is treated with lithium metal in a small specialized research furnace to form lithium carbide (also known as lithium acetylide). The carbide can then be reacted with water, as usual, to form acetylene gas to feed into a mass spectrometer to measure the isotopic ratio of carbon-14 to carbon-12 ...
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